Hello,
ANT does have an internal mechanism that will detect if clock phases are shifting, or if there are encroaching transmissions from other masters in the same RF space. This mechanism is known as coexistence. Please refer to the presentation titled 'ANT Basics' at the bottom of the page
here. I highly recommend taking a look at this video, as it gives a great visual representation of the coexistence mechanism, and it might help clarify the difference between coexistence and frequency agility.
Please note that the coexistence mechanism is for dealing with clock phase shifting between a synchronized master and slave, or dealing with many ANT devices in one area. Frequency Agility is used for dealing with interference in extremely hostile RF environments (i.e. another device's signal is interfering with an ANT transmission, NOT encroaching on the same RF space) by allowing the devices to jump channels when a hostile RF environment is detected. It is not generally recommended that you use frequency agility unless it is absolutely necessary for your application. You can get more information on frequency agility from 'AN10 ANT Frequency Agility Application Note' available
here.
Cheers